The Qualitative Analysis of the Selected Explosives using Thin-Layer Chromatography

Authors

  • Tereza Lutonská NBC Defence Institute, University of Defence, Brno, Czech Republic
  • Z. Kobliha NBC Defence Institute, University of Defence, Brno, Czech Republic
  • Z. Skaličan NBC Defence Institute, University of Defence, Brno, Czech Republic

Keywords:

TLC, Explosive, TNT, RDX, HMX, Tetryl

Abstract

A simple, economical and relatively quick method of thin-layer chromatography (TLC) has been applied to analyse four frequently used explosives, TNT, RDX, HMX and Tetryl that are a common part of significant military, industrial and improvised explosives. Silicon dioxide is proven to separate individual explosives at a stationary phase. Out of 38 tested, three types of two-component mobile phases consisting of petroleum ether and acetone in the ratio of 2:1 or 7:3 of a volume and hexane and acetone in the ratio of 2:1 of a volume are recommended. To detect explosives, the UV radiation with the wavelength of 254 nm is proposed.

References

AGRAWAL, JP. and HODGSON, RD. Organic Chemistry of Explosives. Wiley, 2007. 384 p.

BREBERA, S. Military Explosives and Technology Production of Secondary Explosives (in Czech). Pardubice: University of Pardubice, 2001.

VARGA, R. The Utilization of Modern Analytical Methods in Trace Analysis of Explosives (in Slovak) [PhD Thesis]. Pardubice : University of Pardubice, 2005.

KUBOTA, N. Thermochemical Aspects of Combustion, Propellants and Explosives, 2nd, Completely Revised and Extended Edition, 2006, 530 p.

YINON, J. and BOGUSZ, M. J. Explosives, Forensic Science Handbook of Analytical Separations, 2008, vol. 6. Department of Environmental Science, Chapter 24, p. 823-838.

KIRCHNER, J. G. and PERRY, E. S. Thin Layer Chromatography. New York: Wiley, 1978. 1137 p.

ŠTULÍK, K. Analytical Separation Methods (in Czech). Praha: Karolinum, 2004.

SINGH, B., VERMA, M., VASUDEVA, S. K., SHERA, B. M. L. Analysis of Explosive Mixtures by Thin Layer Chromatography, Def Sci J, 1982, Vol 32, p. 151-155.

GHOLAMIN, F., CHALOOSI, M., HUSAIN, S. W. DEHGHANI, H. Determination of RDX and Keto-RDX in High-Explosive Mixtures by High-

Performance Thin-Layer Chromatography, J. of Planar Chromatography, 2001, vol. 14, p. 296-299.

KRISHNAMURTHY, R., BAKRE, S. M. SHINDE, B., M. Simultaneous Detection of High Explosives in Post-Explosion Debris by HPTLC with Two Successive Mobile Phases, J. of Planar Chromatography, 1999, vol. 12, p. 394-397.

MISZCZAK, M. TLC and Densitometry Application to Determine Quality of High Explosive Mixtures. In 10th Symposium on Chemical problems connected with the Stability of Explosives. 1996, p. 179-185.

HILEY, R. W. Investigations of Thin Layer Chromatographic Techniques Used for Forensic Explosives Analysis in the Early 1970s, Journal of Forensic Science, 1993, vol. 38, no. 4, p. 864-873.

ČSN 66 80 63:1969, Determination of Explosion Temperature of Explosives (in Czech) [on line]. Pardubice : Pardubice University of Pardubice, 2008. 3 p. [cited 2008-03-19]. Available from: <http://eshop.normservis.cz/nahledy/view/csn/66/04996/04996_nahled.pdf>.

LUTONSKÁ, T. Possibilities of TLC for Analyse of Explosives (in Czech) [Diploma Thesis]. Pardubice : University of Pardubice, 2009. 68 p.

Downloads

Published

01-11-2015

How to Cite

Lutonská, T., Kobliha, Z., & Skaličan, Z. (2015). The Qualitative Analysis of the Selected Explosives using Thin-Layer Chromatography. Advances in Military Technology, 10(1), 111–117. Retrieved from https://aimt.cz/index.php/aimt/article/view/1065

Issue

Section

Technical Information

Categories