Use of a Handheld Raman Spectrometer for Identification of Toxic Agents in Clandestine Laboratories

Authors

DOI:

https://doi.org/10.3849/aimt.01809

Keywords:

AEP-66, chemical warfare agent, deployable laboratory, chemical weapons, sampling and identification, precursors

Abstract

Handheld Raman spectrometers are commonly used as fast detectors for preliminary noncontact analysis of a number of chemicals. The article deals with their possible use for military identification of chemical warfare agents and their precursors. Spectra of 29 chemical substances were recorded. Based on the similarity of the spectra in the library, the device was able to automatically detect 20 substances in all measurement methods, 1 substance only in the most transparent containers. By means of external software and the creation of a user’s library, the vibrations of functional groups in the respective molecules were assigned to the individual Raman bands, thereby creating a database that enables the identification of toxic substances.

Author Biography

  • Tomáš Rozsypal, University of Defence

    NBC Defence Institute

References

STANAG 4632: 2005, Deployable NBC Analytical Laboratory.

AEP-66: 2015, NATO Handbook for Sampling and Identification of Biological, Chemical and Radiological Agents.

ROZSYPAL, T. and R. ZAHRADNÍČEK. Comparative Analysis of NATO Re-quirements for Laboratory Identification of Chemical Agents and Military Technical Means for Its Implementation. Advances in Military Technology, 2021, 16(1), pp. 5-17. DOI 10.3849/aimt.01455.

LARKIN, P.J. IR and Raman Spectroscopy: Principles and Spectral Interpreta-tion. New York: Elsevier, 2011. ISBN 0-12-386984-6.

DE ARAUJO, W.R., T.M.G. CARDOSO, R.G. DA ROCHA, M.H.P. SANTANA, R.A.A. MUÑOZ, E.M. RICHTER, T.R.L.C. PAIXÃO and W.K.T. COLTRO. Portable Analytical Platforms for Forensic Chemistry: A review. Analytica Chimica Acta, 2018, 1034, pp. 1-21. DOI 10.1016/j.aca.2018.06.014.

HAKONEN, A., P.O. ANDERSSON, M.S. SCHMIDT, T. RINDZEVICIUS and M. KÄLL. Explosive and Chemical Threat Detection by Surface-Enhanced Raman Scattering: A Review. Analytica Chimica Acta, 2015, 893, pp. 1-13. DOI 10.1016/j.aca.2015.04.010.

PACSIAL-ONG, E.J. and Z.P. AGUILAR. Chemical Warfare Agent Detection: A Review of Current Trends and Future Perspective. Frontiers in Bioscience, 2013, S5(2), pp. 516-543. DOI 10.2741/S387.

WATERBURY, R.D., T. CONGHUYENTONNU, H. HARDY, T. MOLNER, R. ROBINS, M. SCOTT, J.A. GUICHETEAU and C.R. HOWLE. Recent Develop-ment of a New Handheld UV Raman Sensor for Standoff Detection. In: Chemical, Biological, Radiological, Nuclear, and Explosives (CBRNE) Sensing XXII. Society of Photo-Optical Instrumentation Engineers, 2021, 117490I. DOI 10.1117/12.2587656.

)KONDO, T., R. HASHIMOTO, Y. OHRUI, R. SEKIOKA, T. NAGOMI, F. MUTA and Y. SETO. Analysis of Chemical Warfare Agents by Portable Raman Spectrometer with both 785 nm and 1064 nm Excitation. Forensic Science Inter-national, 2018, 291, pp. 23-38. DOI 10.1016/j.forsciint.2018.07.032.

SATOH, T., R. SEKIOKA, Y. SETO, H. MATSUMIYA and H. NAKAGAWA. Analysis of Chemical Warfare Agents by Portable Raman Spectrometer. Analysis Chemistry, 2016, 65(9), pp. 539-545. DOI 10.2116/bunsekikagaku.65.539.

WIKTELIUS, D., L. AHLINDER, A. LARSSON, K.H. HOLMGREN, R. NORLIN and P.O. ANDERSSON. On the Use of Spectra from Portable Raman and ATR-IR Instruments in Synthesis Route Attribution of a Chemical Warfare Agent by Multivariate Modeling. Talanta, 2018, 186, pp. 622-627. DOI 10.1016/j.talanta.2018.02.108.

ROY, E., P.G. WILCOX, S. HOFFLAND and I. PARDOE. Detection of Munitions Grade G-Series Nerve Agents Using Raman Excitation at 1064 nm. In: Proceedings of the SPIE. Toulouse: Society of Photo-Optical Instrumentation Engineers, 2015, 9455. DOI 10.1117/12.2194027.

BRADY, J.J. and P.M. PELLEGRINO. Next Generation Hazard Detection via Ultrafast Coherent Anti-Stokes Raman Spectroscopy. In: Chemical, Biological, Radiological, Nuclear, and Explosives (CBRNE) Sensing XIV. Baltimore: Society of Photo-Optical Instrumentation Engineers, 2013, 8710. DOI 10.1117/

2015838.

NAN, D.-N., L.-Q. DONG, W.-X. FU, W.-W. LIU and J.-L. KONG. Fast Identi-fication of Hazardous Liquids Based on Raman Spectroscopy. Spectroscopy and Spectral Analysis, 2021, 41(6), pp. 1806-1810. DOI 10.3964/j.issn.1000-0593(2021)06-1806-05.

WILCOX, P.G., J.A. GUICHETEAU, A.W. FOUNTAIN, J.A. GUICHETEAU and C.R. HOWLE. Comparison of Handheld Raman Sensors through Opaque Containers. In: Chemical, Biological, Radiological, Nuclear, and Explosives (CBRNE) Sensing XIX. Orlando: Society of Photo-Optical Instrumentation Engi-neers, 2018, 10629. DOI 10.1117/12.2303968.

LIN-VIEN, D., N.B. COLTHUP, W.G. FATELEY and J.G. GRASSELLI. The Handbook of Infrared and Raman Characteristic Frequencies of Organic Mole-cules. New York: Elsevier, 1991. ISBN 978-0-12-451160-6.

CHRISTESEN, S., B.M ACIVER, L. PROCELL, D. SORRICK, M. CARRABBA and J. BELLO. Nonintrusive Analysis of Chemical Agent Identification Sets Using a Portable Fiber-Optic Raman Spectrometer. Applied Spectroscopy, 1999, 53(7), pp. 850-855. DOI 10.1366/0003702991947432.

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Published

26-06-2023

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How to Cite

Rozsypal, T., & Greplová, N. (2023). Use of a Handheld Raman Spectrometer for Identification of Toxic Agents in Clandestine Laboratories. Advances in Military Technology, 18(1), 133-150. https://doi.org/10.3849/aimt.01809

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